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- W2471438032 abstract "Ceramic model catalysts of general formula Bi4V2−xSbxO11−δare synthesised by solid-state reaction. X-ray diffraction shows the materials to be single phase over the composition range 0 ≤ x < 0.3, with a second phase, which is not identified, produced at higher antimony doping level. XPS results show oxidation states of +IV and +V for vanadium in these compounds. These results also indicate that the proportion of antimony on the surface of the compounds is greater than that in the bulk of these compounds. The catalytic properties of the materials are examined using methanol oxidation as a test reaction. The activity and selectivity to formaldehyde production shown by these materials is found to be strongly correlated with the antimony doping level." @default.
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- W2471438032 date "1997-04-01" @default.
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- W2471438032 title "Catalytic Properties of Bi4V2−xSbxO11−δin Methanol Oxidation" @default.
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- W2471438032 doi "https://doi.org/10.1006/jcat.1997.1559" @default.
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