Matches in SemOpenAlex for { <https://semopenalex.org/work/W2471458649> ?p ?o ?g. }
- W2471458649 endingPage "6244" @default.
- W2471458649 startingPage "6233" @default.
- W2471458649 abstract "To explore the influence of the charge/polarity of Keggin polyanions and coordination modes of transition metal cations on the construction of polyoxometalate (POM)-based hybrid compounds, we design two synthetic routes and obtain six new POM-based inorganic–organic hybrid compounds, namely, [Co5(H2O)6(bimb)8(PWVI10WV2O40)2]·14H2O (1), [Co2(bimb)2(GeW12O40)][bimb]·2H2O (2), [Co2(bimb)2(BW12O40)][Hbimb]·2H2O (3), [Co2(bimb)2(H2W12O40)][H2bimb]·2H2O (4), [Cu(bimb)(BW12O40)][H2bimb]2·2H2O (5) and [Ag2(bimb)2(BW12O40)][H3bimb]·2H2O (6) (bimb = 1,4-bis(1-imidazolyl)benzene). All compounds were characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction. Compound 1 represents the first POM-based three-dimensional (3D) self-penetrating structure composed of a unique metal–organic polycatenated framework and tridentate Keggin clusters. Compounds 2, 3, 4 and 6 are isostructural, which show POMOF structures consisting of Keggin cluster guests and a metal–organic nanotube host. The structure of compound 5 is a simple 2D grid layer. The isolation of the title compounds is very informative for systematically understanding the effect of the charge/polarity of POMs and coordination modes of transition metal cations on the structures of POM-based hybrids. The effect of the charge/polarity of POMs and coordination modes of transition metal cations is discussed in this work. Additionally, the luminescence and electrochemical properties of 1–6 have been investigated in detail." @default.
- W2471458649 created "2016-07-22" @default.
- W2471458649 creator A5000867921 @default.
- W2471458649 creator A5003314041 @default.
- W2471458649 creator A5023460508 @default.
- W2471458649 creator A5035259025 @default.
- W2471458649 creator A5056356646 @default.
- W2471458649 creator A5065772702 @default.
- W2471458649 creator A5084358851 @default.
- W2471458649 date "2016-01-01" @default.
- W2471458649 modified "2023-09-30" @default.
- W2471458649 title "The factors affecting the assembly of Keggin–metal–bimb systems: charge/polarity of Keggin polyanions and coordination modes of metal cations" @default.
- W2471458649 cites W1431852377 @default.
- W2471458649 cites W1754688606 @default.
- W2471458649 cites W1756260249 @default.
- W2471458649 cites W1807859153 @default.
- W2471458649 cites W1870547570 @default.
- W2471458649 cites W1903036010 @default.
- W2471458649 cites W1913589860 @default.
- W2471458649 cites W1928828209 @default.
- W2471458649 cites W1959811121 @default.
- W2471458649 cites W1963769471 @default.
- W2471458649 cites W1963781542 @default.
- W2471458649 cites W1965643379 @default.
- W2471458649 cites W1967309570 @default.
- W2471458649 cites W1968601669 @default.
- W2471458649 cites W1969142803 @default.
- W2471458649 cites W1974906487 @default.
- W2471458649 cites W1976291286 @default.
- W2471458649 cites W1977367831 @default.
- W2471458649 cites W1979358924 @default.
- W2471458649 cites W1986387513 @default.
- W2471458649 cites W1986524780 @default.
- W2471458649 cites W1987936810 @default.
- W2471458649 cites W1989476775 @default.
- W2471458649 cites W1999514260 @default.
- W2471458649 cites W2000100567 @default.
- W2471458649 cites W2000129846 @default.
- W2471458649 cites W2007442038 @default.
- W2471458649 cites W2012305612 @default.
- W2471458649 cites W2012447879 @default.
- W2471458649 cites W2015119510 @default.
- W2471458649 cites W2015122610 @default.
- W2471458649 cites W2018564314 @default.
- W2471458649 cites W2018630066 @default.
- W2471458649 cites W2018817543 @default.
- W2471458649 cites W2019219373 @default.
- W2471458649 cites W2023914025 @default.
- W2471458649 cites W2026980723 @default.
- W2471458649 cites W2027059234 @default.
- W2471458649 cites W2028411336 @default.
- W2471458649 cites W2038687870 @default.
- W2471458649 cites W2039753302 @default.
- W2471458649 cites W2040499279 @default.
- W2471458649 cites W2041625793 @default.
- W2471458649 cites W2041775689 @default.
- W2471458649 cites W2045134400 @default.
- W2471458649 cites W2047993755 @default.
- W2471458649 cites W2053015481 @default.
- W2471458649 cites W2055123703 @default.
- W2471458649 cites W2055730303 @default.
- W2471458649 cites W2061130432 @default.
- W2471458649 cites W2064679727 @default.
- W2471458649 cites W2064745104 @default.
- W2471458649 cites W2067114632 @default.
- W2471458649 cites W2074019256 @default.
- W2471458649 cites W2075258785 @default.
- W2471458649 cites W2076276700 @default.
- W2471458649 cites W2087697683 @default.
- W2471458649 cites W2090467001 @default.
- W2471458649 cites W2093693707 @default.
- W2471458649 cites W2093738858 @default.
- W2471458649 cites W2098655131 @default.
- W2471458649 cites W2107409366 @default.
- W2471458649 cites W2121264884 @default.
- W2471458649 cites W2133964865 @default.
- W2471458649 cites W2138973783 @default.
- W2471458649 cites W2154467305 @default.
- W2471458649 cites W2155966063 @default.
- W2471458649 cites W2156721448 @default.
- W2471458649 cites W2161847143 @default.
- W2471458649 cites W2310788654 @default.
- W2471458649 cites W2312239075 @default.
- W2471458649 cites W2312323031 @default.
- W2471458649 cites W2312726892 @default.
- W2471458649 cites W2313876009 @default.
- W2471458649 cites W2317897064 @default.
- W2471458649 cites W2321643509 @default.
- W2471458649 cites W2322077392 @default.
- W2471458649 cites W2322906400 @default.
- W2471458649 cites W2323963066 @default.
- W2471458649 cites W2324073065 @default.
- W2471458649 cites W2324289733 @default.
- W2471458649 cites W2328070910 @default.
- W2471458649 cites W2332597521 @default.
- W2471458649 cites W2333218752 @default.
- W2471458649 cites W2333300041 @default.
- W2471458649 cites W2334441888 @default.