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- W2471493817 abstract "When sulphur to which after recrystallisation no air has had access is melted, or when ammonia is led for a few minutes through ordinary sulphur after it has been melted, the two forms of liquid sulphur (yellow, mobile S λ , and brown, viscous S μ ) adjust themselves very rapidly to those proportions which are in equilibrium at that temperature to which the liquid may have been raised. The adjustment occupies but a few moments. When specimens thus prepared are then chilled by plunging into water, the reversion of the S μ to S λ is equally rapid, and therefore the product is wholly brittle, crystalline, monoclinic sulphur. This behaviour is observed whether the liquid has been heated at, say, 155°, where the amount of S μ , at equilibrium is 7·2 per cent., or at 448°, where the amount is at least 34 per cent." @default.
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- W2471493817 date "1906-01-01" @default.
- W2471493817 modified "2023-10-18" @default.
- W2471493817 title "Further Study of the two Forms of Liquid Sulphur as Dynamic Isomers" @default.
- W2471493817 doi "https://doi.org/10.1017/s0370164600024640" @default.
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