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• W2471602912 startingPage "1862" @default.
• W2471602912 abstract "Janadolide, a new cyclic polyketide–peptide hybrid possessing a tert-butyl group, was isolated from an Okeania sp. marine cyanobacterium. The gross structure was elucidated by spectroscopic analyses, and the absolute configurations of the amino acid moieties were determined by acid hydrolysis and chiral-phase HPLC analyses. The absolute configuration of the two stereogenic centers in the polyketide moiety was elucidated based on a combination of degradation reactions and spectroscopic analyses including the phenyl-glycine methyl ester method. Janadolide showed potent antitrypanosomal activity with an IC50 value of 47 nM without cytotoxicity against human cells at 10 μM." @default.
• W2471602912 created "2016-07-22" @default.
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• W2471602912 date "2016-06-30" @default.
• W2471602912 modified "2023-10-18" @default.
• W2471602912 title "Janadolide, a Cyclic Polyketide–Peptide Hybrid Possessing a <i>tert</i>-Butyl Group from an <i>Okeania</i> sp. Marine Cyanobacterium" @default.
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• W2471602912 doi "https://doi.org/10.1021/acs.jnatprod.6b00171" @default.
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