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- W2471645124 abstract "The photo-oxidation of 4-methoxybenzyl methyl sulfide (1a), benzyl methyl sulfide (1b), and 4-cyanobenzyl methyl sulfide (1c) has been investigated in the presence of N-methoxy phenanthridinium hexafluorophosphate (MeOP(+)PF6(-)) under nitrogen in CH3CN. The steady-state photolysis experiments showed for the investigated sulfides exclusively the formation of the corresponding benzaldehyde as the oxidation product, reasonably due to a deprotonation of the sulfide radical cations. Photo-oxidation of 1a-1c occurs through an electron transfer process. Indeed, laser flash photolysis measurements showed an efficient formation of sulfide radical cations, detected in their dimeric form [(4-X-C6H4CH2SCH3)2(+•)] at ≈520 nm. At longer delay times, the absorption of the dimer radical cation was replaced by an absorption band assigned to the (α-thio)benzyl cation (thionium ion, λmax = 420-400 nm), formed by oxidation of the benzyl radical and not by that of the (α-thiomethyl)benzyl radical, as expected if a Cα-H bond cleavage is operative. This finding highlights a particular stability of this kind of cation never reported before, even though its involvement in one-electron oxidation mechanisms of various sulfides has already been invoked. Density functional theory calculations allowed identification of a significant charge and spin delocalization involving both the phenyl ring and the sulfur atom of the radical cations." @default.
- W2471645124 created "2016-07-22" @default.
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- W2471645124 date "2015-08-13" @default.
- W2471645124 modified "2023-10-18" @default.
- W2471645124 title "Photoinduced One-Electron Oxidation of Benzyl Methyl Sulfides in Acetonitrile: Time-Resolved Spectroscopic Evidence for a Thionium Ion Intermediate" @default.
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- W2471645124 doi "https://doi.org/10.1021/acs.joc.5b01052" @default.
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