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- W2471962332 abstract "A new solution based route for depositing Cu2ZnSnS4 (CZTS) thin films is described, focusing on the effects of Sb and Na codoping. X-ray diffraction and Raman spectroscopy confirm formation of the kesterite phase with a measurable improvement in crystallinity upon doping. A sharp band gap absorption edge at 1.4 eV is determined from diffuse reflectance measurements, while improvement in the photoluminescence yield and sharpening of the band-to-band emission spectra are observed in the presence of Na and Sb. The performance of devices with the configuration glass/Mo/CZTS/CdS/i-ZnO/ZnO:Al/Ni–Al and total area of 0.5 cm2 is reported. Analysis of over 200 cells shows that introduction of Na and Sb leads to an increase of the average power conversion efficiency from 3.2 ± 0.6 to 5.2 ± 0.3%. The best cell with efficiency of 5.7% is obtained upon Na and Sb doping, featuring 14.9 mA cm–2 short-circuit current, 610 mV open circuit voltage, and 63% fill factor under simulated AM 1.5 illumination. This performance r..." @default.
- W2471962332 created "2016-07-22" @default.
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- W2471962332 date "2016-07-06" @default.
- W2471962332 modified "2023-10-17" @default.
- W2471962332 title "Cu<sub>2</sub>ZnSnS<sub>4</sub> Thin Films Generated from a Single Solution Based Precursor: The Effect of Na and Sb Doping" @default.
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- W2471962332 doi "https://doi.org/10.1021/acs.chemmater.6b01499" @default.
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