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- W2472786334 abstract "Herein, we report a tetraphenylethylene-diglycine (TPE-GG) hydrogelator from a systematic study of TPE-capped dipeptides with various amphiphilic properties. From a chemical design, we found that the hydrogelation of TPE-GG molecules can be utilized to generate supramolecular nanostructures with a large TPE-based nanobelt width (∼300 nm) and lateral dimension ratio (>30 fold). In addition, TPE-GG has the lowest molecular weight and minimum number of atoms compared to any TPE-capped peptide hydrogelator reported to date. This minimal self-assembled hydrogelator can fundamentally achieve the gel features compared with other TPE-capped peptides. A combined experimental and computational study indicates the π–π interactions, electrostatic interactions and hydrogen-bonding interactions are the major driving forces behind the formation of self-assembled nanobelts. This study demonstrates the importance of structure–property relationships and provides new insights into the design of supramolecular nanomaterials." @default.
- W2472786334 created "2016-07-22" @default.
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- W2472786334 date "2016-01-01" @default.
- W2472786334 modified "2023-10-17" @default.
- W2472786334 title "A novel nanostructured supramolecular hydrogel self-assembled from tetraphenylethylene-capped dipeptides" @default.
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- W2472786334 doi "https://doi.org/10.1039/c6sm00755d" @default.
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