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- W2472887127 abstract "In (1,4,7,10,13,16-hexaoxacyclooctadecane)rubidium hexachloridoantimonate(V), [Rb(C 12 H 24 O 6 )][SbCl 6 ], (1), and its isomorphous caesium {(1,4,7,10,13,16-hexaoxacyclooctadecane)caesium hexachloridoantimonate(V), [Cs(C 12 H 24 O 6 )][SbCl 6 ]}, (2), and ammonium {ammonium hexachloridoantimonate(V)–1,4,7,10,13,16-hexaoxacyclooctadecane (1/1), (NH 4 )[SbCl 6 ]·C 12 H 24 O 6 }, (3), analogues, the hexachloridoantimonate(V) anions and 18-crown-6 molecules reside across overline{3} axes passing through the Sb atoms and the centroids of the 18-crown-6 groups, both of which coincide with centres of inversion. The Rb + [in (1)], Cs + [in (2)] and NH 4 + [in (3)] cations are situated inside the cavity of the 18-crown-6 ring; they are situated on overline{3} axes and are equally disordered about centres of inversion, deviating from the centroid of the 18-crown-6 molecule by 0.4808 (13), 0.9344 (7) and 0.515 (8) Å, respectively. Interaction of the ammonium cation and the 18-crown-6 group is supported by three equivalent hydrogen bonds [N...O = 2.928 (3) Å and N—H...O = 162°]. The centrosymmetric structure of [Cs(18-crown-6)] + , with the large Cs + cation approaching the centre of the ligand cavity, is unprecedented and accompanied by unusually short Cs—O bonds [2.939 (2) and 3.091 (2) Å]. For all three compounds, the [ M (18-crown-6)] + cations and [SbCl 6 ] − anions afford linear stacks along the c axis, with the cationic complexes embedded between pairs of inversion-related anions." @default.
- W2472887127 created "2016-07-22" @default.
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- W2472887127 date "2015-09-18" @default.
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- W2472887127 title "Unusual centrosymmetric structure of [<i>M</i>(18-crown-6)]<sup>+</sup>(<i>M</i>= Rb, Cs and NH<sub>4</sub>) complexes stabilized in an environment of hexachloridoantimonate(V) anions" @default.
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- W2472887127 doi "https://doi.org/10.1107/s2053229615015430" @default.
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