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• W2473300539 abstract "A stereoselective bioreduction of 2-oxocycloalkanecarbonitriles was concurrently coupled to a whole cell-catalyzed nitrile hydrolysis in one-pot. The first step, mediated by ketoreductases, involved a dynamic reductive kinetic resolution, which led to 2-hydroxycycloalkanenitriles in very high enantio- and diastereomeric ratios. Then, the simultaneous exposure to nitrile hydratase and amidase from whole cells of Rhodococcus rhodochrous provided the corresponding 2-hydroxycycloalkanecarboxylic acids with excellent overall yield and optical purity for the all-enzymatic cascade." @default.
• W2473300539 created "2016-07-22" @default.
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• W2473300539 date "2016-06-30" @default.
• W2473300539 modified "2023-10-18" @default.
• W2473300539 title "Developing a Biocascade Process: Concurrent Ketone Reduction-Nitrile Hydrolysis of 2-Oxocycloalkanecarbonitriles" @default.
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• W2473300539 doi "https://doi.org/10.1021/acs.orglett.6b01510" @default.
• W2473300539 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27357900" @default.
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