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- W2473463251 abstract "The mechanical properties of calcium fumarate trihydrate, a 1D coordination polymer considered for use as a calcium source for food and beverage enrichment, have been determined via nanoindentation and high-pressure X-ray diffraction with single crystals. The nanoindentation studies reveal that the elastic modulus (16.7-33.4 GPa, depending on crystallographic orientation), hardness (1.05-1.36 GPa), yield stress (0.70-0.90 GPa), and creep behavior (0.8-5.8 nm/s) can be rationalized in view of the anisotropic crystal structure; factors include the directionality of the inorganic Ca-O-Ca chain and hydrogen bonding, as well as the orientation of the fumarate ligands. High-pressure single-crystal X-ray diffraction studies show a bulk modulus of ∼ 20 GPa, which is indicative of elastic recovery intermediate between small molecule drug crystals and inorganic pharmaceutical ingredients. The combined use of nanoindentation and high-pressure X-ray diffraction techniques provides a complementary experimental approach for probing the critical mechanical properties related to tableting of these dietary supplements." @default.
- W2473463251 created "2016-07-22" @default.
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- W2473463251 date "2015-11-20" @default.
- W2473463251 modified "2023-10-16" @default.
- W2473463251 title "Mechanical Properties of a Calcium Dietary Supplement, Calcium Fumarate Trihydrate" @default.
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- W2473463251 doi "https://doi.org/10.1021/acs.inorgchem.5b01466" @default.
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