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- W2473588259 abstract "Arrhenius's theory of electrolytic dissociation, proposed in 1887, gave the first great impetus to chemical kinetics, and led to an understanding of catalysis by acids and bases. Later the Debye-Hückel theory of strong electrolytes and G.N. Lewis's definition of ionic strength led to a satisfactory interpretation of the kinetic effects of added foreign salts. These effects showed that, when transition-state theory is applied, the rate of a second-order reaction between A and B must involve a kinetic activity factor yAyB/y≠, where yA and yB are the activity coefficients of the reactants and y≠ is the activity coefficient of the activated complex. The detection of general acid-base catalysis was consistent with the Brønsted-Lowry extended definition of general acids and bases." @default.
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- W2473588259 date "1989-01-01" @default.
- W2473588259 modified "2023-09-27" @default.
- W2473588259 title "The Contribution of Electrochemistry to the Development of Chemical Kinetics" @default.
- W2473588259 doi "https://doi.org/10.1021/bk-1989-0390.ch005" @default.
- W2473588259 hasPublicationYear "1989" @default.
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