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• W2473669445 endingPage "6854" @default.
• W2473669445 startingPage "6848" @default.
• W2473669445 abstract "A chemoselective oxidative cleavage of synthetic gracilioether B, 11-epi-gracilioether C benzoate, and des-hydroxygracilioether C with pyridinium chlorochromate, which proceeds with loss of the furanyl acetate, has enabled total synthesis and stereochemical elucidation of the marine sponge metabolites (4R,6R)-plakilactone C, (4R,6R,9R)-plakilactone B, and (4R,6R)-des-hydroxyplakilactone B. des-Hydroxygracilioether C, the putative biosynthetic precursor to hippolachnin A, was also found to undergo a facile ene cyclization on treatment with SnCl4." @default.
• W2473669445 created "2016-07-22" @default.
• W2473669445 creator A5036603961 @default.
• W2473669445 creator A5069480591 @default.
• W2473669445 date "2016-07-21" @default.
• W2473669445 modified "2023-09-26" @default.
• W2473669445 title "Total Synthesis of Plakilactones C, B and <i>des</i>-Hydroxyplakilactone B by the Oxidative Cleavage of Gracilioether Furanylidenes" @default.
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• W2473669445 doi "https://doi.org/10.1021/acs.joc.6b01196" @default.
• W2473669445 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27359169" @default.
• W2473669445 hasPublicationYear "2016" @default.
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