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- W2474085685 abstract "In the present paper we discuss the importance of gold nanoparticles in heterogeneous catalysis and show their different roles as active phases, electronic promoters and poisoning deactivators. In particular, some examples of our recent experience are presented: i) Gold nanoparticles as active sites: the LT-WGSR. In this example gold acts as the active phase, and catalytic performances are strongly related to gold nanosizes. ii) Gold nanoparticles as electronic promoters: the H 2 O 2 direct synthesis. In this example gold nanoparticles are inactive for the reaction, while they are able to increase selectivity since they act as electronic promoters. iii) Gold nanoparticles as poisoning deactivators: the TPA purification. In this example gold nanoparticles are not active for the reaction but have an important role in delaying deactivation by sulphur poisoning." @default.
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- W2474085685 date "2013-01-01" @default.
- W2474085685 modified "2023-09-23" @default.
- W2474085685 title "A golden perspective for catalysis" @default.
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- W2474085685 doi "https://doi.org/10.7361/scicf-500" @default.
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