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- W2474725270 abstract "The considerably conjugated π systems of the group 14 dithienometallole-linked ethynylene-conjugated porphyrin dimers (1Ms) were described based on comprehensive experimental and theoretical studies. The electronic absorption spectra of 1M displayed a large splitting in the Soret band and a red-shifted Q-band, indicating that the dithienometallole spacer was effective in facilitating the porphyrin-porphyrin electronic coupling. Torsional planarization behaviors of 1M were observed in the time-resolved fluorescence spectra. Density functional theory (DFT) calculations revealed that the dithienometallole spacer is an ideal partner for the ethynylene-conjugated porphyrin to produce fully delocalized highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels due to their similar HOMO and LUMO levels. Finally, 1M exhibited a strong propensity for the quinoidal-cummulenic conjugation in the dithienometallole spacer when in a photoexcited state." @default.
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- W2474725270 date "2016-07-13" @default.
- W2474725270 modified "2023-10-17" @default.
- W2474725270 title "Group 14 Dithienometallole-Linked Ethynylene-Conjugated Porphyrin Dimers" @default.
- W2474725270 cites W1971350904 @default.
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- W2474725270 cites W1989003213 @default.
- W2474725270 cites W1995740258 @default.
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- W2474725270 cites W2023271753 @default.
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- W2474725270 cites W2028381510 @default.
- W2474725270 cites W2032020387 @default.
- W2474725270 cites W2033562953 @default.
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- W2474725270 doi "https://doi.org/10.1021/acs.inorgchem.6b00667" @default.
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