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• W2474801085 startingPage "10022" @default.
• W2474801085 abstract "Reported is the first oxy-trifluoromethylation of allylamines with carbon dioxide (CO2 ) using copper catalysis, thus leading to important CF3 -containing 2-oxazolidones. It is also the first time CO2 , a nontoxic and easily available greenhouse gas, has been used to tune the difunctionalization of alkenes from amino- to oxy-trifluoromethylation. Of particular note, this multicomponent reaction is highly chemo-, regio-, and diastereoselective under redox-neutral and mild reaction conditions. Moreover, these reactions feature good functional-group tolerance, broad substrate scope, easy scalability and facile product diversification. The important products could also be formed with either spirocycles or two adjacent tetrasubstituted carbon centers." @default.
• W2474801085 created "2016-07-22" @default.
• W2474801085 creator A5005367449 @default.
• W2474801085 creator A5012093734 @default.
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• W2474801085 creator A5059599037 @default.
• W2474801085 creator A5063216145 @default.
• W2474801085 creator A5074239305 @default.
• W2474801085 creator A5074262763 @default.
• W2474801085 creator A5074909943 @default.
• W2474801085 date "2016-07-14" @default.
• W2474801085 modified "2023-10-10" @default.
• W2474801085 title "Selective Oxytrifluoromethylation of Allylamines with CO₂" @default.
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