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- W2474821826 abstract "The $N$-heterocyclic carbene (NHC)--Ag(I) complexes 3a-c were synthesized from benzimidazolium chlorides (2a-c = NHC.HCl), incorporating benzyl derivatives and a 2-methoxyethyl group (a: $^{3}$N = 2,4,6-trimethylbenzyl; b: $^{3}$N = 2,3,5,6-tetramethylbenzyl; c: $^{3}$N = pentamethylbenzyl). The compounds were characterized by spectroscopic and elemental analyses. The synthesized NHC-Ag(I) complexes (3a-c) were tested as catalysts for the catalytic three-component coupling reaction of aldehyde, alkyne, and amine to propargylamines in various solvents. All complexes were active catalysts for catalytic three-component coupling reactions with good yields under neat and mild conditions (after 4 h, yields of up to 94%)." @default.
- W2474821826 created "2016-07-22" @default.
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- W2474821826 date "2016-01-01" @default.
- W2474821826 modified "2023-09-30" @default.
- W2474821826 title "Ag(I) complexes of benzimidazol-2-ylidene ligands: a study of catalytic efficiency towards three-component coupling reactions" @default.
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- W2474821826 doi "https://doi.org/10.3906/kim-1510-6" @default.
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