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• W2474833344 abstract "We report that an exceptionally large volume of highly ordered arrays (single grains) on the order of millimeters in scale can be rapidly created through a unique innate guiding mechanism of brush block copolymers (BBCPs). The grain volume is over 109 times larger than that of typical self-assembled linear BCPs (LBCPs). The use of strong interactions between nanoparticles (NPs) and BBCPs enables high loadings of functional materials, up to 76 wt % (46 vol %) in the target domain, while maintaining excellent long-range order. Overall, this work provides a simple method to precisely control the spatial orientation of functionalities at nanometer length scales over macroscopic volumes, thereby enabling the production of hybrid materials for many important applications." @default.
• W2474833344 created "2016-07-22" @default.
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• W2474833344 date "2015-09-23" @default.
• W2474833344 modified "2023-09-27" @default.
• W2474833344 title "Large-Volume Self-Organization of Polymer/Nanoparticle Hybrids with Millimeter-Scale Grain Sizes Using Brush Block Copolymers" @default.
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• W2474833344 doi "https://doi.org/10.1021/jacs.5b08632" @default.
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