Matches in SemOpenAlex for { <https://semopenalex.org/work/W2474833588> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2474833588 endingPage "21172" @default.
- W2474833588 startingPage "21165" @default.
- W2474833588 abstract "Several Ag–S nanoclusters where the cluster core comprises mixed metal (main component) and sulfur atoms show superatomic orbitals in the conduction band edge. However, there are no superatomic states, i.e., delocalized electrons, in the valence band, and the clusters in question can be labeled as “zerovalent”. We show here an example of an Ag–S cluster which fulfills the superatom model and has delocalized electrons: The recently synthesized and characterized [Ag62S12(StBu)32]2+ cluster has four delocalized valence electrons based on a simple counting rule, and we compare it to the zerovalent cluster [Ag62S13(StBu)32]4+. Our electronic structure analysis confirms the existence of superatomic states in the valence and conduction bands, but the locations of these states do not agree completely with the conventional prediction based on the spherical Jellium model. [Ag62S12(StBu)32]2+ displays the 1S2 electronic shell closure at the Fermi energy instead of the 1S21P2 configuration as suggested by its electro..." @default.
- W2474833588 created "2016-07-22" @default.
- W2474833588 creator A5016409082 @default.
- W2474833588 creator A5063386882 @default.
- W2474833588 date "2015-08-26" @default.
- W2474833588 modified "2023-10-16" @default.
- W2474833588 title "Superatom Model for Ag–S Nanocluster with Delocalized Electrons" @default.
- W2474833588 cites W1967853451 @default.
- W2474833588 cites W1978634069 @default.
- W2474833588 cites W1980807995 @default.
- W2474833588 cites W1981368803 @default.
- W2474833588 cites W1983852130 @default.
- W2474833588 cites W2022085321 @default.
- W2474833588 cites W2022504800 @default.
- W2474833588 cites W2056319595 @default.
- W2474833588 cites W2066778093 @default.
- W2474833588 cites W2069807403 @default.
- W2474833588 cites W2077228161 @default.
- W2474833588 cites W2088499999 @default.
- W2474833588 cites W2096868202 @default.
- W2474833588 cites W2108299472 @default.
- W2474833588 cites W2114661560 @default.
- W2474833588 cites W2115803851 @default.
- W2474833588 cites W2118875032 @default.
- W2474833588 cites W2140537016 @default.
- W2474833588 cites W2161313073 @default.
- W2474833588 cites W2276525825 @default.
- W2474833588 cites W2307833820 @default.
- W2474833588 cites W2315395656 @default.
- W2474833588 cites W2317087285 @default.
- W2474833588 cites W2320490605 @default.
- W2474833588 cites W2329082285 @default.
- W2474833588 cites W2330814207 @default.
- W2474833588 cites W2332766234 @default.
- W2474833588 cites W4234750540 @default.
- W2474833588 doi "https://doi.org/10.1021/acs.jpcc.5b05824" @default.
- W2474833588 hasPublicationYear "2015" @default.
- W2474833588 type Work @default.
- W2474833588 sameAs 2474833588 @default.
- W2474833588 citedByCount "4" @default.
- W2474833588 countsByYear W24748335882016 @default.
- W2474833588 countsByYear W24748335882017 @default.
- W2474833588 countsByYear W24748335882019 @default.
- W2474833588 countsByYear W24748335882021 @default.
- W2474833588 crossrefType "journal-article" @default.
- W2474833588 hasAuthorship W2474833588A5016409082 @default.
- W2474833588 hasAuthorship W2474833588A5063386882 @default.
- W2474833588 hasConcept C121332964 @default.
- W2474833588 hasConcept C147120987 @default.
- W2474833588 hasConcept C159467904 @default.
- W2474833588 hasConcept C171250308 @default.
- W2474833588 hasConcept C171706072 @default.
- W2474833588 hasConcept C185592680 @default.
- W2474833588 hasConcept C192562407 @default.
- W2474833588 hasConcept C2778402822 @default.
- W2474833588 hasConcept C62520636 @default.
- W2474833588 hasConcept C70050531 @default.
- W2474833588 hasConceptScore W2474833588C121332964 @default.
- W2474833588 hasConceptScore W2474833588C147120987 @default.
- W2474833588 hasConceptScore W2474833588C159467904 @default.
- W2474833588 hasConceptScore W2474833588C171250308 @default.
- W2474833588 hasConceptScore W2474833588C171706072 @default.
- W2474833588 hasConceptScore W2474833588C185592680 @default.
- W2474833588 hasConceptScore W2474833588C192562407 @default.
- W2474833588 hasConceptScore W2474833588C2778402822 @default.
- W2474833588 hasConceptScore W2474833588C62520636 @default.
- W2474833588 hasConceptScore W2474833588C70050531 @default.
- W2474833588 hasFunder F4320321108 @default.
- W2474833588 hasFunder F4320322400 @default.
- W2474833588 hasIssue "36" @default.
- W2474833588 hasLocation W24748335881 @default.
- W2474833588 hasOpenAccess W2474833588 @default.
- W2474833588 hasPrimaryLocation W24748335881 @default.
- W2474833588 hasRelatedWork W117828233 @default.
- W2474833588 hasRelatedWork W2001257671 @default.
- W2474833588 hasRelatedWork W2012567322 @default.
- W2474833588 hasRelatedWork W2110811268 @default.
- W2474833588 hasRelatedWork W2177619098 @default.
- W2474833588 hasRelatedWork W2217190501 @default.
- W2474833588 hasRelatedWork W2325336714 @default.
- W2474833588 hasRelatedWork W2474833588 @default.
- W2474833588 hasRelatedWork W2885905440 @default.
- W2474833588 hasRelatedWork W4206166681 @default.
- W2474833588 hasVolume "119" @default.
- W2474833588 isParatext "false" @default.
- W2474833588 isRetracted "false" @default.
- W2474833588 magId "2474833588" @default.
- W2474833588 workType "article" @default.