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• W2474855774 startingPage "19047" @default.
• W2474855774 abstract "It is highly desirable to prevent crack formation in polymeric materials at an early stage and to extend their lifespan, particularly when repairs to these materials would be difficult for humans. Here, we designed and synthesized catechol-functionalized polymers that can self-heal in seawater through hydrogen bonding and coordination. These bioinspired acrylate polymers are originally viscous materials, but after coordination with environmentally safe, common metal cations in seawater, namely, Ca2+ and Mg2+, the mechanical properties of the polymers were greatly enhanced from viscous to tough, hard materials. Reduced swelling in seawater compared with deionized water owing to the higher osmotic pressure resulted in greater toughness (∼5 MPa) and self-healing efficiencies (∼80%)." @default.
• W2474855774 created "2016-07-22" @default.
• W2474855774 creator A5008141701 @default.
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• W2474855774 date "2016-07-12" @default.
• W2474855774 modified "2023-10-01" @default.
• W2474855774 title "Seawater-Assisted Self-Healing of Catechol Polymers via Hydrogen Bonding and Coordination Interactions" @default.
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• W2474855774 doi "https://doi.org/10.1021/acsami.6b04075" @default.
• W2474855774 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27377859" @default.
• W2474855774 hasPublicationYear "2016" @default.
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