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- W2474868162 abstract "Abstract A new 1:2-type inorganic–organic hybrid CuII CeIII heterometallic germanotungstate (GT) derivative KNa2H9[enH2]2 [Cu(en)2(H2O)]2[Cu(en)2]2{Cu(en)2[Ce(α-GeW11O39)2]2}·14H2O (1) (en = ethylenediamine) was obtained by simultaneously introducing Cu2 + and Ce4 + cations to the trivacant Keggin-type [A-α-GeW9O34]10 − system in the help of extra Na2WO4·2H2O and en ligand under hydrothermal conditions and was further characterized by elemental analyses, IR spectrum, thermogravimetric (TG) analysis and single-crystal X-ray diffraction. 1 exhibits a 1-D CuII CeIII heterometallic chain architecture by tetrameric {Cu(en)2[Ce(α-GeW11O39)2]2}24 − units via K+ cations. Moreover, its solid-state electrochemical and electrocatalytic properties have been measured in 0.5 mol L− 1 Na2SO4 + H2SO4 aqueous solution by entrapping them in a carbon paste electrode, indicating that 1 displays apparent electrocatalytic activities for nitrite, bromate and hydrogen peroxide reduction." @default.
- W2474868162 created "2016-07-22" @default.
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- W2474868162 date "2016-09-01" @default.
- W2474868162 modified "2023-10-16" @default.
- W2474868162 title "Synthesis, structure and electrochemical properties of an inorganic–organic hybrid Cu II Ce III heterometallic germanotungstate" @default.
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- W2474868162 doi "https://doi.org/10.1016/j.inoche.2016.07.002" @default.
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