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- W2475952639 abstract "The chemistry of alkenes is one of the pillars of organic chemistry. These substrates undergo many synthetically useful transformations such as electrophilic and nucleophilic additions, oxidations, reductions, [1þ2] and [2þ2]-cycloadditions, metathesis, polymerizations [1]. This chemistry also applies to dienes and higher polyenes. Conjugated dienes undergo specific reactions, such as conjugated additions and [4þ2]-cycloadditions (DielsAlder reactions) that have found important synthetic applications [1]. However, the double bonds of nonconjugated dienes behave as two separate alkenes in most reactions, an exception being 1,5-dienes that undergo Cope and Claisen rearrangements [1]. In particular, C–C double bonds in 1,4-dienes tend to react as two separated entities in most of the reactions mentioned above, although a few specific reactions of compounds containing the 1,4-diene have been observed in the chemistry of some natural products such as polyunsaturated fatty acids and prostaglandins. The photochemical reactivity of alkenes is also of great interest [1,2]. Studies in this area have led to an expansion of the synthetic utility of these substances. Typical photochemical reactions include cis-trans isomerizations, interand intramolecular cycloadditions, photooxidations, and electrocyclic ring opening and closing of conjugated dienes and polyenes. Many of these photoreactions have thermal counterparts. In contrast, 1,4-dienes can undergo a unique photochemical transformation affording" @default.
- W2475952639 created "2016-08-23" @default.
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- W2475952639 date "2004-11-30" @default.
- W2475952639 modified "2023-10-16" @default.
- W2475952639 title "Di-p-Methane Rearrangement" @default.
- W2475952639 cites W1497399712 @default.
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- W2475952639 doi "https://doi.org/10.1201/9780203997369-9" @default.
- W2475952639 hasPublicationYear "2004" @default.
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