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- W2476179412 abstract "This report describes a process to produce vinyl acetate with high selectivity from exclusively methanol, carbon monoxide, and hydrogen. The simplest scheme for this process involves esterifying acetic acid with methanol, converting the methyl acetate with syn gas directly to ethylidene diacetate and acetic acid, and finally, thermal elimination of acetic acid. Produced acetic acid is recycled. Each step proceeds in high conversion and selectivity. The single step conversion of methyl acetate to ethylidene diacetate is catalyzed by either a palladium or rhodium compound, a source of iodide, and a promoter. The mechanism is described as involving the concurrent generation of acetaldehyde and acetic anhydride which subsequently react to form ethylidene diacetate. An alternative to this scheme involves independent generation of acetaldehyde by reductive carbonylation of methanol or methyl acetate, or by acetic anhydride reduction. The acetaldehyde is then reacted with anhydride in a separate step." @default.
- W2476179412 created "2016-08-23" @default.
- W2476179412 creator A5045154350 @default.
- W2476179412 creator A5046865936 @default.
- W2476179412 date "1987-12-16" @default.
- W2476179412 modified "2023-10-14" @default.
- W2476179412 title "Production of Vinyl Acetate from Methanol and Synthesis Gas" @default.
- W2476179412 doi "https://doi.org/10.1021/bk-1987-0328.ch010" @default.
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