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- W2476276546 abstract "The photoionization of indole in water was studied at 262 nm by the femtosecond transient absorption technique. The initial excited state generated by one-photon absorption is about 0.4 eV above the photoionization threshold of indole in water. Under these near-threshold conditions ionization most likely occurs by an electron-transfer mechanism in which an electron is directly transferred to a trapping site in the solvent without the intermediate generation of a delocalized electron in the conduction band of water. Solvated electrons were formed within our time resolution (≈ 200 fs). No recombination between the solvated electron and the indole radical cation could be observed up to 600 ps after the pump pulse, despite the very high electron affinity of the latter species. A similar result was obtained for aqueous tryptophan. The absence of diffusion-limited charge recombination for this highly exergonic reaction is consistent with Marcus-inverted behavior. Introduction Photoionization is a" @default.
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- W2476276546 date "2002-06-03" @default.
- W2476276546 modified "2023-09-23" @default.
- W2476276546 title "Near-Threshold Photoionization Dynamics of Indole in Water" @default.
- W2476276546 doi "https://doi.org/10.1021/bk-2002-0820.ch009" @default.
- W2476276546 hasPublicationYear "2002" @default.
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