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- W2476378426 abstract "1,8-Bis(TRPN)methylanthracene, available from 1,8-dibromomethylanthracene, binds phosphate and pyrophosphate anions in aqueous solution, pH 7, with signalling in the form of chelation enhanced fluorescence. The affinity of this convergent chemosensor for pyrophosphate (Kd= 2.9 μM) is over 2000-times that for phosphate (Kd= 6.3 mM); a reference nonconvergent chemosensor [1-mono(TRPN)methylanthracene] displays only a 100-fold difference in binding affinities. The ion discrimination thus realized permits real-time analysis in the hydrolysis of pyrophosphate by inorganic pyrophosphatase. It has been known for almost 35 years that catechol complexes reversibly to boronic acids. We observe that 2-anthrylboronic acid complexes catechol in water with Kd 330 μM and concomitant 20-fold reduction in fluorescence intensity. L-DOPA and dopamine behave similarly, suggesting a mechanism for the development of real-time sensing schemes." @default.
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- W2476378426 date "1994-07-16" @default.
- W2476378426 modified "2023-10-13" @default.
- W2476378426 title "Fluorescent Chemosensors of Ion and Molecule Recognition" @default.
- W2476378426 doi "https://doi.org/10.1021/bk-1994-0561.ch027" @default.
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