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- W2476489968 abstract "A two-step self-assembly methodology has been used to obtain 2D coordination polymers with an egg-crate structure of trigonal symmetry and space group R3̅m. The polymers have the molecular formula [Ag3(L1)3(hmt)]X3 (L1 = bis(pyrazol-1-yl)(pyridin-4-yl)methane; hmt = hexamethylenetetramine; X = BF4, ClO4, PF6). In the first step, the previously reported box-like cyclic dimers [Ag L1]2X2, in which the ligands L1 are in a head-to-tail disposition, were obtained and these were subsequently reacted with the base hexamethylenetetramine to form Ag–N(hmt) bonds. The dimers act as linear connectors and the bases as triconnected nodes to give slightly undulating hexagons that form honeycomb sheets. The sheets follow an ABCABC stacking arrangement along [001] so that between them two types of large cavities arise which are occupied by disordered solvent, e.g., DMF inherited from synthesis. The anions, which participate in the formation of the cavities, interact with the sheets through hydrogen bonds. The polymers can be activated by removing the solvents without collapsing, which enabled an evaluation of these materials for use as gas adsorption, anion exchange, and proton capture systems." @default.
- W2476489968 created "2016-08-23" @default.
- W2476489968 creator A5011680821 @default.
- W2476489968 creator A5015192058 @default.
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- W2476489968 creator A5025609196 @default.
- W2476489968 creator A5056722668 @default.
- W2476489968 creator A5070276095 @default.
- W2476489968 date "2015-06-22" @default.
- W2476489968 modified "2023-10-13" @default.
- W2476489968 title "Robust 2D Coordination Networks from a Two-Step Assembly Process with Predesigned Silver Cyclic Dimers and Hexamethylenetetramine" @default.
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