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- W2477172014 abstract "In a discharge in a static reactor, initial pressures of mixtures of H2 + CO of 12 and 50 torr gave conversions of CO to CH4 + C2H2 of approximately 20% for reaction times of 1/2 to four minutes. When water was added to the reactants, formation of hydrocarbons was repressed. Conversion of CO was increased to more than 90% when the reaction products were removed by a cold trap as they formed. With H2 + CO2, no hydrocarbons were formed unless water was frozen out. The different conversions of CO and CO2 can be explained by assuming that the reaction reaches a stationary state or pseudo-equilibrium. When reaction products are removed from the discharge by being frozen out, the stationary state shifts according to Le Chatelier's principle and more hydrocarbons are formed." @default.
- W2477172014 created "2016-08-23" @default.
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- W2477172014 date "1969-06-01" @default.
- W2477172014 modified "2023-10-01" @default.
- W2477172014 title "Hydrocarbons from H<sub>2</sub> + CO and H<sub>2</sub> + CO<sub>2</sub> in Microwave Discharges: Le Chatelier's Principle in Discharge Reactions" @default.
- W2477172014 doi "https://doi.org/10.1021/ba-1969-0080.ch021" @default.
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