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- W2477613116 abstract "A series of tellurium(II) coordination complexes of the general formulas [TeL2,X2] TeL4]X2 (L = thiourea or substituted thiourea; X = CI, Br, SCN) and [Te(S2X)2] (X = COR, CN(C2H5), P(OCH3),P(OCH3)2 P(OC2H5)2 P(C6H11)2 have been prepared and evaluated as image precursors in solution and dry amplification elements. Non-aqueous solutions of the thiourea complexes depit Te(0) at room temperature, Te(0), Pd(0) and Ag(0) being effective catalysts for the reaction. The Te(n) xanthates, Te(S2COR)2(R=CH3,C2H5, i-C3H7,n-C3H7,n-C5H11,C12H25), undergo facile catalytic thermal decomposition to Te(0), Ag(0), Pd(0) and Te(0) being effective catalysts for such processes. The mechanism of the thermal decomposition of [Te(s2CO-i-C3H7)2], has been shown by X-ray photoelectron spectroscopy to involve an intramolecular thermal ligand reduction reaction to give oxidized sulphur ligand (i.e. i-C3H7O-C(S)SSC(S)O-i-C3H7) and Te(0), ESCA experiments have also demonstrated that the amplification process is autocatalytic." @default.
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- W2477613116 date "1982-03-01" @default.
- W2477613116 modified "2023-09-23" @default.
- W2477613116 title "Non-Silver Amplification Processes: Part 3. Catalytic Thermal Decomposition of Te(II) Coordination Complexes via Internal Redox Reactions" @default.
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- W2477613116 doi "https://doi.org/10.1080/00223638.1982.11738156" @default.
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