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- W2477798049 abstract "In recent years, controlled/living polymerization has become an important synthetic method to prepare complex architecture of polymers. These methods allow control over the functionality, molecular structure, and molecular weight of the polymeric materials for use in specific applications. The molecular weight and the molecular weight distribution can be controlled by adjusting the polymerization temperature and time. The most prominent methods are nitroxide mediated polymerization (NMP), stable free radical polymerization, atom transfer radical polymerization, reversible addition-fragmentation chain transfer (RAFT), etc. While living cationic polymerization of vinyl monomers is normally assumed to proceed only under strictly anhydrous conditions, in the last decade or so, this process has been carried out in aqueous media or in the presence of water. In this article, these and other aspects of living cationic polymerization process development as well as other similar processes is presented." @default.
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- W2477798049 date "2016-01-01" @default.
- W2477798049 modified "2023-09-25" @default.
- W2477798049 title "Living Cationic Polymerization" @default.
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- W2477798049 doi "https://doi.org/10.1016/b978-0-12-803581-8.03749-8" @default.
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