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- W2478132317 abstract "This talk will focus on the nature of bonding of fullerenes with other materials as demonstrated by synchrotron radiation and x-ray photoemission. Adsorption of C{sub 60} on metallic and semiconducting substrates occurs via charge transfer from the substrate to a LUMO-derived resonance, resulting in Fermi level alignment and dipole formation. Bonding of metal atoms to C{sub 60} depends on the metal work function and bulk cohesive energy. Evaporation of high cohesive energy materials onto a fullerene substrate results in metal cluster nucleation and limited C{sub 60} disruption for transition metals. Low cohesive energy metals form compounds with a degree of ionic character related to the metal work function. Photoemission results show the formation of ionic K-fulleride compounds while greater hybridization is observed for Ca-rich fullerides. Finally the electronic structure of fluorinated and hydrogenated fullerenes demonstrate changes in states derived from C{sub 60} {pi} bonds due to reaction of dangling bonds." @default.
- W2478132317 created "2016-08-23" @default.
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- W2478132317 date "1993-12-31" @default.
- W2478132317 modified "2023-09-23" @default.
- W2478132317 title "Chemical bonding and electronic structure of fullerene-based compounds" @default.
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