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- W2478185978 abstract "A pentamethylcyclopentadienyl-iridium complex containing a tricyclic, dianionic, tridentate, scorpionate (facial binding), mixed organic-inorganic ligand was synthesized and characterized by single-crystal X-ray crystallography, as well as polynuclear NMR, UV-vis, and IR spectroscopies. The central cycle of the tridentate ligand consists of a modified boroxine in which two of the boron centers are tetrahedral, anionic borates. The complex is stable to hydrolysis in aqueous solution for >9 weeks at 25 °C but reacts with a 50 mM solution of sodium periodate within 12 s to form a periodate-driven oxygen evolution catalyst that has a turnover frquency of >15 s(-1). However, the catalyst is almost completely deactivated within 5 min, achieving an average turnover number of ca. 2500 molecules of oxygen per atom of iridium. Nanoparticles were not observed on this time scale but did form within 4 h of catalyst activation under these experimental conditions. The parent complex was modeled using density functional theory, which accurately reflected the geometry of the complex and indicated significant interaction of iridium- and boracycle-centered orbitals." @default.
- W2478185978 created "2016-08-23" @default.
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- W2478185978 date "2016-07-27" @default.
- W2478185978 modified "2023-10-09" @default.
- W2478185978 title "Organometallic Iridium Complex Containing a Dianionic, Tridentate, Mixed Organic–Inorganic Ligand" @default.
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- W2478185978 doi "https://doi.org/10.1021/acs.inorgchem.6b01218" @default.
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