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• W2479113897 abstract "A highly efficient synthetic route to pterocarpenes and coumestans is described. BCl3-mediated dehydrative cyclization of 1,3-diaryloxyacetones under mild conditions permitted regioselective ring closure to afford 3-((2-iodoaryloxy)methyl)benzofurans which were converted to the corresponding pterocarpenes by Pd-catalyzed intramolecular direct arylation. The subsequent benzylic oxidation led to coumestans. This sequence was applied to the formal syntheses of coumestrol and the proposed structure of plicadin as well as total syntheses of flemichapparins B and C." @default.
• W2479113897 created "2016-08-23" @default.
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• W2479113897 date "2016-01-01" @default.
• W2479113897 modified "2023-10-16" @default.
• W2479113897 title "Syntheses of pterocarpenes and coumestans via regioselective cyclodehydration" @default.
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• W2479113897 doi "https://doi.org/10.1039/c6ob01451h" @default.
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