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• W2479205143 abstract "It is commonly agreed that the crystalline structure of seeds dictates the crystallinity of final nanoparticles in a seeded-growth process. Although the formation of monocrystalline particles does require the use of single-crystal seeds, twin planes may stem from either single- or polycrystalline seeds. However, experimental control over twin-plane formation remains difficult to achieve synthetically. Here, we show that a careful interplay between kinetics and selective surface passivation offers a unique handle over the emergence of twin planes (in decahedra and triangles) during the growth over single-crystalline gold nanoparticles of quasi-spherical shape. Twinning can be suppressed under conditions of slow kinetics in the presence of silver ions, yielding single-crystalline particles with high-index facets." @default.
• W2479205143 created "2016-08-23" @default.
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• W2479205143 date "2016-08-03" @default.
• W2479205143 modified "2023-10-18" @default.
• W2479205143 title "Silver Ions Direct Twin-Plane Formation during the Overgrowth of Single-Crystal Gold Nanoparticles" @default.
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• W2479205143 doi "https://doi.org/10.1021/acsomega.6b00066" @default.
• W2479205143 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5026459" @default.
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• W2479205143 hasPublicationYear "2016" @default.
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