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- W2479238980 abstract "The stability of furfuryl mercaptan (Fur-SH) was studied in aqueous solutions in the presence of reagents for the Fenton reaction. The impact of hydrogen peroxide, iron, ascorbic acid, and EDTA was studied by incubating them in various combinations with Fur-SH for 1 h at 37°C. About 80% of Fur-SH was lost in the presence of hydrogen peroxide (H2O2) and the ferrous iron generating system Fe(III) and ascorbic acid. Volatile components formed were mainly dimers of Fur-SH, i.e. Fur-Sn-Fur with n = 1-3, difurfuryl disulfide being the major compound. In the model systems containing Fe(II) and H2O2, the volatiles generated account for about 1/3 of the total Fur-SH lost. Electron paramagnetic resonance spectroscopy in the presence of the spin traps POBN, DMPO, and DEPMPO indicated the formation of hydroxyl and carbon-centered radicals arising from H2O2 and Fur-SH, respectively." @default.
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- W2479238980 date "2000-01-15" @default.
- W2479238980 modified "2023-09-25" @default.
- W2479238980 title "Degradation of Furfuryl Mercaptan in Fenton-Type Model Systems" @default.
- W2479238980 cites W1678232890 @default.
- W2479238980 doi "https://doi.org/10.1021/bk-2000-0754.ch024" @default.
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