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- W2479451780 abstract "Abstract The present study investigated the co-solubilization of three representative low-brominated diphenyl ethers (low-BDEs) in nonionic surfactant micelles. Co-solubilization effects were quantified in terms of molar solubilization ratio (MSR), micelle–water partition coefficient (log K m ), extent of synergism/inhibition (R ΔMSR ), first stepwise association constant ( K 1 ), the average number of solute molecules per micelle ( S M ), excess Gibbs energy (ΔG0 excess), and interaction parameter (ω/RT). The solubilities of low-BDEs during co-solubilization were increased (i.e., synergism) in all of the surfactants tested, relative to their respective solubilities during solubilization. In each surfactant system, synergism was weaker for BDE-15/BDE-28 than that for BDE-15/BDE-47 because BDE-15 and BDE-28 may be partitioned more uniformly in the micelle core than BDE-47, which increased the possibility of their competition. Unexpectedly, BDE-28 and BDE-47 with similar log K ow values demonstrated enhanced co-solubility. This phenomenon was attributed to the positive electrostatic potentials of bromines (computed by Gaussian program) on BDE-28 and BDE-47 which may provide additional attractions to oxygen atoms of the hydrophilic chains. The synergism observed for BDE-15/BDE-28 and BDE-15/BDE-47 was stronger in the Brij35 system than that in Brij58 and Brij78 systems, suggesting that a surfactant with lower aggregation number and/or longer hydrophilic chain length can avoid the competition between solutes for the micelle core. This study may improve the understanding of multi-solutes interactions in surfactant micelles." @default.
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- W2479451780 date "2016-11-01" @default.
- W2479451780 modified "2023-10-17" @default.
- W2479451780 title "Synergistic solubilization of low-brominated diphenyl ether mixtures in nonionic surfactant micelles" @default.
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- W2479451780 doi "https://doi.org/10.1016/j.molliq.2016.07.108" @default.
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