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- W2479465027 abstract "Low-temperature efficient hydrogenation of C═O bonds in various compounds, which is one of the most important processes for producing fuels and chemicals, is of fundamental interest but remains a significant challenge. The primary problem is a lack of heterogeneous catalyst systems that are highly active at ambient or low temperatures. This paper describes an efficient strategy for designing a low-temperature hydrogenation catalyst. Ru nanoparticles supported on reduced graphene oxide (Ru/RGO) show remarkable efficiency for hydrogenation of levulinic acid into γ-valerolactone at temperatures as low as −10 °C. The catalyst is also highly active toward low-temperature hydrogenation of C═O bonds in other carbonyl compounds into C–OH bonds, such as furfural, propionaldehyde, 2-pentanone, hydroxyacetone, acetone, acetophenone, cyclohexanone, and benzophenone. X-ray photoelectron spectroscopy and in situ Fourier transform infrared demonstrate that the electron transfer between Ru0 and RGO leads to the formation of an electron-rich state of Ru0 nanoparticles that are highly effective for activating C═O bonds." @default.
- W2479465027 created "2016-08-23" @default.
- W2479465027 creator A5000251609 @default.
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- W2479465027 date "2015-11-16" @default.
- W2479465027 modified "2023-10-06" @default.
- W2479465027 title "Graphene-Modified Ru Nanocatalyst for Low-Temperature Hydrogenation of Carbonyl Groups" @default.
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- W2479465027 doi "https://doi.org/10.1021/acscatal.5b02170" @default.
- W2479465027 hasPublicationYear "2015" @default.
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