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- W2479661696 abstract "Small angle neutron scattering, SANS, was used in situ to determine the anisotropic shear ordering of polyelectrolytic, liquid crystalline cellulose microfibrils in aqueous (D2O) suspension. The inter-rod distance of microfibrils under shear scales with C-1/2 at high concentration, C. Orientational order parameters were calculated from the angular spread of the anisotropic SANS scattering peaks. Changes in the order parameter as a function of shear rate correlate to changes in the viscosity/shear rate profile. Particle alignment increases with increasing shear rate, yet the highest degree of alignment for microfibrils (with axial ratios of ~45) was observed a short period after the cessation of shear flow. Relaxation occurred far more rapidly for shorter microfibrils with axial ratio of ~30." @default.
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- W2479661696 date "1995-05-05" @default.
- W2479661696 modified "2023-10-17" @default.
- W2479661696 title "Shear-Induced Alignment of Liquid-Cystalline Suspensions of Cellulose Microfibrils" @default.
- W2479661696 doi "https://doi.org/10.1021/bk-1995-0597.ch023" @default.
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