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• W2479676137 abstract "Isothermal titration micro-calorimeter has been used to measure the enthalpy change (q) of polyhydroxy solutes [(+)-d-xylose, xylitol, (+)-d-glucose, 2-deoxy-d-glucose, (+)-methyl-α-d-glucopyranoside, and (+)-maltose monohydrate] in water and in (0.05, 0.15, and 0.25) mol·kg−1 l-ascorbic acid(aq) solutions at (288.15, 298.15, 308.15, and 318.15) K. Limiting enthalpies of dilution (ΔdilH°) of these solutes were calculated from heat evolved/absorbed during calorimetric experiments. Further thermodynamic quantities such as limiting enthalpies of dilution of transfer (ΔtrΔdilH°), change in heat capacity (ΔdilCop,2,m), and pair (hAB) and triplet (hABB) enthalpic interaction coefficients were also calculated and used to explore the nature of interactions of solutes with cosolute (l-ascorbic acid). The Jones-Dole viscosity B-coefficients for (+)-d-xylose, xylitol, (+)-d-galactose, galactitol, (+)-d-glucose, 2-deoxy-d-glucose, (+)-methyl-α-d-glucopyranoside, and (+)-maltose monohydrate in water and in (0.05, 0.15, 0.25, and 0.35) mol·kg−1 l-ascorbic acid(aq) solutions have been determined from viscosity (η) data measured over temperature range (288.15–318.15) K and at pressure, P = 101.3 kPa. The temperature dependence of B-coefficients (dB/dT), and viscosity B-coefficients of transfer (ΔtrB) of solutes from water to cosolute have also been estimated. These parameters have been discussed in terms of structure-making (kosmotropic) or -breaking (chaotropic) behavior of solutes." @default.
• W2479676137 created "2016-08-23" @default.
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• W2479676137 date "2016-11-01" @default.
• W2479676137 modified "2023-09-26" @default.
• W2479676137 title "Investigations to explore interactions in (polyhydroxy solute + l -ascorbic acid + H 2 O) solutions at different temperatures: Calorimetric and viscometric approach" @default.
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• W2479676137 doi "https://doi.org/10.1016/j.jct.2016.07.020" @default.
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