Matches in SemOpenAlex for { <https://semopenalex.org/work/W247974368> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W247974368 abstract "A synthesis has been developed for monothio-/beta/-diketones with geminal fluoroalkyl and mercapto groups. These compounds were found to exist in solution in an enolenethiol equilibrium. The fraction of the enethiol form increases with increasing solution polarity. The ionization constants of the compounds obtained in 95:5 water-ethanol ranged from 3.4 to 4.0 pK/sub a/ units, which is 0.5-2.0 units less than the pK/sub a/ values of the corresponding /gamma/-isomers. The authors have shown that phenyl-substituted compounds are formed in low yields upon the reaction of the corresponding /beta/-aminovinyl ketones with hydrogen sulfide in an aprotic solvent (diethyl ether) under acid catalysis conditions." @default.
- W247974368 created "2016-06-24" @default.
- W247974368 creator A5010053248 @default.
- W247974368 creator A5014055054 @default.
- W247974368 creator A5034528506 @default.
- W247974368 creator A5087488333 @default.
- W247974368 date "1988-06-10" @default.
- W247974368 modified "2023-09-24" @default.
- W247974368 title "Synthesis, prototropic tautomerism, and ionization constants of new polyfluorinated monothio-/beta/-diketones" @default.
- W247974368 hasPublicationYear "1988" @default.
- W247974368 type Work @default.
- W247974368 sameAs 247974368 @default.
- W247974368 citedByCount "0" @default.
- W247974368 crossrefType "journal-article" @default.
- W247974368 hasAuthorship W247974368A5010053248 @default.
- W247974368 hasAuthorship W247974368A5014055054 @default.
- W247974368 hasAuthorship W247974368A5034528506 @default.
- W247974368 hasAuthorship W247974368A5087488333 @default.
- W247974368 hasConcept C111233374 @default.
- W247974368 hasConcept C145148216 @default.
- W247974368 hasConcept C155647269 @default.
- W247974368 hasConcept C161790260 @default.
- W247974368 hasConcept C178790620 @default.
- W247974368 hasConcept C179104552 @default.
- W247974368 hasConcept C185592680 @default.
- W247974368 hasConcept C198291218 @default.
- W247974368 hasConcept C2779758233 @default.
- W247974368 hasConcept C2780161600 @default.
- W247974368 hasConcept C2780407432 @default.
- W247974368 hasConcept C2780471494 @default.
- W247974368 hasConceptScore W247974368C111233374 @default.
- W247974368 hasConceptScore W247974368C145148216 @default.
- W247974368 hasConceptScore W247974368C155647269 @default.
- W247974368 hasConceptScore W247974368C161790260 @default.
- W247974368 hasConceptScore W247974368C178790620 @default.
- W247974368 hasConceptScore W247974368C179104552 @default.
- W247974368 hasConceptScore W247974368C185592680 @default.
- W247974368 hasConceptScore W247974368C198291218 @default.
- W247974368 hasConceptScore W247974368C2779758233 @default.
- W247974368 hasConceptScore W247974368C2780161600 @default.
- W247974368 hasConceptScore W247974368C2780407432 @default.
- W247974368 hasConceptScore W247974368C2780471494 @default.
- W247974368 hasLocation W2479743681 @default.
- W247974368 hasOpenAccess W247974368 @default.
- W247974368 hasPrimaryLocation W2479743681 @default.
- W247974368 hasRelatedWork W1491705046 @default.
- W247974368 hasRelatedWork W1895634803 @default.
- W247974368 hasRelatedWork W1971273914 @default.
- W247974368 hasRelatedWork W1971539721 @default.
- W247974368 hasRelatedWork W1971951577 @default.
- W247974368 hasRelatedWork W1972754248 @default.
- W247974368 hasRelatedWork W1974460881 @default.
- W247974368 hasRelatedWork W1977198302 @default.
- W247974368 hasRelatedWork W1985177004 @default.
- W247974368 hasRelatedWork W2008891363 @default.
- W247974368 hasRelatedWork W2020115837 @default.
- W247974368 hasRelatedWork W2028003924 @default.
- W247974368 hasRelatedWork W2074046573 @default.
- W247974368 hasRelatedWork W2105614562 @default.
- W247974368 hasRelatedWork W2124428290 @default.
- W247974368 hasRelatedWork W2171111105 @default.
- W247974368 hasRelatedWork W2950192160 @default.
- W247974368 hasRelatedWork W2950774514 @default.
- W247974368 hasRelatedWork W2951513715 @default.
- W247974368 hasRelatedWork W3006392429 @default.
- W247974368 isParatext "false" @default.
- W247974368 isRetracted "false" @default.
- W247974368 magId "247974368" @default.
- W247974368 workType "article" @default.