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- W2479746957 abstract "The dynamics of texture transformations in the nematic phase of a comb-shaped polymer possessing a combined structure with mesogenic groups in both main and side chains was studied by method of the Freedericksz threshold transitions in a magnetic field. The rotational viscosity y 1 * was determined and studied as a function of the temperature and molecular mass M for seven polymer fractions with M = 900-10200. It was found that the activation energy for the polymer orientation for M ≥ 2000 is virtually independent of the molecular mass and is several times greater than the values typical of low-molecular-mass liquid crystals. The dependence of the rotational viscosity on the molecular mass is described by a power function with the exponent β = 1.5 ± 0.1, The conformation of macromolecules in a nematic melt is discussed. The results are compared to the analogous data available for linear and other comb-shaped polymers." @default.
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- W2479746957 date "2001-01-01" @default.
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- W2479746957 title "Dynamics of the Fréedericksz threshold transitions and the rotational viscosity of a thermotropic nematic phase of a combined comb-shaped polymer" @default.
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