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• W2479807673 abstract "An efficient catalytic system has been established for the asymmetric boron conjugate addition of B2pin2 onto α-functionalized (involving C, N, O, and Cl) α,β-unsaturated carbonyls under mild, neutral conditions involving Cu[(S)-(R)-ppfa]Cl, AgNTf2, and alcohols. The dual additives of AgNTf2 and alcohols were found to play crucial roles for achieving high catalytic activity and enantio- and diastereoselectivity (up to 98% ee and 70:1 dr)." @default.
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• W2479807673 date "2016-07-19" @default.
• W2479807673 modified "2023-10-17" @default.
• W2479807673 title "Asymmetric Catalytic Enantio- and Diastereoselective Boron Conjugate Addition Reactions of α-Functionalized α,β-Unsaturated Carbonyl Substrates" @default.
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• W2479807673 doi "https://doi.org/10.1021/acs.orglett.6b01998" @default.
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