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- W2480077881 abstract "Hydrophobic interactions of sodium poly(styrenesulfonate) compounds (NaPSS) of different sulfonation were investigated. One was commercially available and was considered to be less than 85% degree of sulfonation. The other was prepared in our laboratory from sodium styrenesulfonate monomer and was considered to be 100% sulfonation. Column was Shodex PROTEIN KW-804 packed with glycerylpropylgroup bonded silica gel. Mobile phase was sodium phosphate buffer at pH 7.0 at different ionic strengths. Calibration plots for these two types of NaPSS pullulan showed that retention volumes of NaPSS increased with increasing the ionic strength, but the extent was different between two types of NaPSS. Hydrophobicity of low sulfonated NaPSS was originated from both unreacted phenyl groups and the backbone C-C linkage. Highly sulfonated NaPSS still exhibited some hydrophobicity which may be originated from the backbone C-C linkage." @default.
- W2480077881 created "2016-08-23" @default.
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- W2480077881 date "1996-05-30" @default.
- W2480077881 modified "2023-09-25" @default.
- W2480077881 title "Comparison of Secondary Effects in Aqueous Size Exclusion Chromatography Between Sodium Poly(styrenesulfonate) Compounds of Different Sulfonations" @default.
- W2480077881 doi "https://doi.org/10.1021/bk-1996-0635.ch018" @default.
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