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- W2480322404 endingPage "16398" @default.
- W2480322404 startingPage "16356" @default.
- W2480322404 abstract "Resonance-assisted hydrogen bonding (RAHB), a concept introduced by Gilli and co-workers in 1989, concerns a kind of intramolecular H-bonding strengthened by a conjugated π-system, usually in 6-, 8-, or 10-membered rings. This Review highlights the involvement of RAHB as a driving force in the synthesis of organic, coordination, and organometallic compounds, as a handy tool in the activation of covalent bonds, and in starting moieties for synthetic transformations. The unique roles of RAHB in molecular recognition and switches, E/Z isomeric resolution, racemization and epimerization of amino acids and chiral amino alcohols, solvatochromism, liquid-crystalline compounds, and in synthons for crystal engineering and polymer materials are also discussed. The Review can provide practical guidance for synthetic chemists that are interested in exploring and further developing RAHB-assisted synthesis and design of materials." @default.
- W2480322404 created "2016-08-23" @default.
- W2480322404 creator A5050017915 @default.
- W2480322404 creator A5081571915 @default.
- W2480322404 date "2016-08-05" @default.
- W2480322404 modified "2023-09-23" @default.
- W2480322404 title "Resonance-Assisted Hydrogen Bonding as a Driving Force in Synthesis and a Synthon in the Design of Materials" @default.
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