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- W2480374290 abstract "Diffusion limitations due to triiodide transport through nanoporous TiO 2 networks are investigated with the help of a simple device structure, a nanoporous TiO 2 layer directly sintered onto a platinum electrode and immersed in an I - 3 /I - electrolyte solution. At voltages below 0.3 V, electronic transport in this device is dominated by the catalytic reaction at the Pt/electrolyte interface whereas above approximately 0.4 V current flow is limited by diffusion of triiodide through the nanoporous TiO 2 network. Through the analysis of devices with different TiO 2 layer thicknesses and I 2 concentrations we calculate a diffusion constant for I - 3 of 1.24 (′0.02) X 10 - 5 cm 2 s - 1 in the bulk of the electrolyte and an effective diffusion constant of 0.44 (′0.02) X 10 - 5 cm 2 s - 1 within the pores of the TiO 2 network." @default.
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- W2480374290 date "2003-01-01" @default.
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- W2480374290 title "Diffusion Limitations to I[sub 3][sup −]/I[sup −] Electrolyte Transport Through Nanoporous TiO[sub 2] Networks" @default.
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- W2480374290 doi "https://doi.org/10.1149/1.1570032" @default.
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