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- W2480504145 abstract "The effect of different substituents on the kinetics of the reactions between 2-amino-benzamide and some of benzaldehyde derivatives have been spectrally investigated in the presence of formic acid. The proposed mechanism were challenged due to the determination of rate-determining step (RDS) and also, to obtain the general rate law of the reaction. For all substituents, the reactions followed the second-order kinetics and the partial orders of reactions were recognized with respect to each reactant. Electron withdrawing substituents on benzaldehyde ring increased the rate of reaction. Kinetic values (k and Ea) and associated activation parameters (ΔH‡, ΔG‡ and ΔS‡) of the reactions were determined. Both the Arrhenius and the Eyring equations were used to calculate activation energy. Comparison of magnitude of and T showed that the reactions were enthalpy controlled. Isokinetic plots for the reactions were plotted and linear relationship between and recognized that relative contribution of enthalpy and entropy to the overall free energy was the same in the reactions." @default.
- W2480504145 created "2016-08-23" @default.
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- W2480504145 date "2016-07-28" @default.
- W2480504145 modified "2023-09-25" @default.
- W2480504145 title "An experimental investigation of substituent effects on the formation of 2,3-dihydroquinazolin-4(1<i>H</i>)-ones: a kinetic study" @default.
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- W2480504145 doi "https://doi.org/10.1002/poc.3616" @default.
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