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- W2480691370 abstract "observed upon heating of NH/sub 4/NO/sub 3/ to produce N/sub 2/, H/sub 2/O, and nitrous oxides. Plutonium nitrate contains hydration water. This water is of some concern due to the production of hydrogen by alpha-radiolysis. Two waters of hydration appear to be the lower limit to which Pu(NO/sub 3/)/sub 4/ . XH/sub 2/O may be taken before decomposition of the solid begins. TGA results indicate the simple nitrate (Pu(NO/sub 3/)/sub 4/ . XH/sub 2/O) is somewhat less thermally stable than either the ammonium or potassium hexanitrato plutonate which detracts somewhat from its suitability as a shipping form. Maintaining large quantities of this compound with a high /sup 238/Pu content (less than 1 percent /sup 238/Pu) may require specially designed and larger containers to prevent thermal degradation and gas pressure buildup problems. The informaion was presented to plutonium processors; the final consensus of this group was that in spite of some thermal instability of Pu(NO/sub 3/)/sub 4/ . XH/sub 2/O at fairly low temperatures, it was preferable to K/sub 2/Pu(NO/sub 3/)/sub 6/ due to the additional waste disposal problems the potassium would present. (Pu(NO/sub 3/)/sub 4/ . XH/sub 2/O also has several other advantages. A possible problem that could arise due to the variable weight of plutonium nitrate could be in plutonium accountability, but this would be prevented if the plutonium content of the solution prior to evaporation to the solid is known. (DLC)" @default.
- W2480691370 created "2016-08-23" @default.
- W2480691370 creator A5014614077 @default.
- W2480691370 date "1965-01-22" @default.
- W2480691370 modified "2023-10-18" @default.
- W2480691370 title "THE FATIGUE BEHAVIOR OF Pu-1.0 w/o Ga DELTA-STABILIZED PLUTONIUM" @default.
- W2480691370 doi "https://doi.org/10.2172/4640686" @default.
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