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- W2480883612 abstract "Surface chemistry, topography, and mechanical properties all influence biological response to materials. This chapter introduces the techniques of X-ray Photoelectron Spectroscopy (XPS) and Secondary Ion Mass Spectrometry (SIMS), which provide complementary information on the chemistry of surfaces. Examples presented in the chapter are chosen from the literature on biomaterials production and characterization, specifically polymers, to highlight the issues involved in data acquisition and to illustrate some important concepts of data analysis. It is necessary to first specify that the surface is different from the bulk. For many materials, the chemistry at the surface is very different, for example, distinct oxide films are formed under ambient conditions on many metals, such as stainless steel. The surface chemistry of pure single phase polymers, analyzed in the vacuum of SIMS or XPS spectrometers, is similar to the bulk structure. Large differences have, however, been observed between the bulk and surface of multi-component polymer formulations due to the mobility of polymer chains combined with the thermodynamic driving force to minimize surface energy." @default.
- W2480883612 created "2016-08-23" @default.
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- W2480883612 date "2007-01-01" @default.
- W2480883612 modified "2023-09-23" @default.
- W2480883612 title "Characterisation using X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS)" @default.
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- W2480883612 doi "https://doi.org/10.1533/9781845693817.1.176" @default.
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