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- W2481335738 abstract "The literature contains numerous references to the reactive copolymers of 2,3-epoxy-1-propyl esters such as 2,3-epoxy-1-propyl methacrylate, acrylate and vinylsulfonate with other vinyl compounds like propionitrile, methyl acrylate, and vinylbenzene (1), and to the addition reaction of amino, carboxy, and hydroxy compounds with the epoxy ring of these copolymers (2). 2,3-Epoxy-1-propyl-2-propenyl ether is found (2) to have a strong tendency to limit the molecular weight of a polymer by chain transfer through the allyl portion of the molecule. Relatively little attention has been paid to the copolymers of 2,3-epoxy-1-propyl ethers such as 1-ethenyl-4-(2,3-epoxy-1-propoxy) benzene, and to the self-addition reaction of the epoxy group with catalytic or reactive functional groups, being capable of opening or adding to the epoxy ring, in the copolymers. This paper, therefore, reports the radical copolymerization of 2,3-epoxy-1-propyl methacrylate or 1-ethenyl-4-(2,3-epoxy-1-propoxy)benzene with 4- and 2-vinylpyridines and with 5-ethyl-2-vinylpyridine, and the self-crosslinking reaction of these copolymers. Experimental Reagent-grade 2,3-epoxy-1-propyl" @default.
- W2481335738 created "2016-08-23" @default.
- W2481335738 creator A5020432791 @default.
- W2481335738 date "1979-12-03" @default.
- W2481335738 modified "2023-10-14" @default.
- W2481335738 title "Self-Cross-Linkable Polyepoxides" @default.
- W2481335738 doi "https://doi.org/10.1021/bk-1979-0114.ch014" @default.
- W2481335738 hasPublicationYear "1979" @default.
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