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• W24816498 abstract "The interference of separation high voltage with the electrochemical detection is a major challenge to the microchip capillary electrophoresis-electrochemical detection systems with end-channel detection mode. Using dopamine and catechol as model analytes, the influences of channel cross-sectional area and channel-to-electrode distance on the high-voltage interference, accordingly on the separation and detection performances of the microchip capillary electrophoresis-electrochemical detection system were investigated. With the increase of the channel cross-sectional area from 312 through 450-615 microm2, the apparent half-wave potentials of hydrodynamic voltammetry for dopamine at the field strength of 288 V/cm shifted positively from 285 through 330-400 mV. By using a chip with the smallest channel cross-section (312 microm2 with top width of 37.3 microm and depth of 8.9 microm) the residual high-voltage field in the detection cell was small, so that detection was conducted at a channel-to-electrode distance of 20 microm to achieve better performances of separation and detection." @default.
• W24816498 created "2016-06-24" @default.
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• W24816498 date "2005-07-01" @default.
• W24816498 modified "2023-09-23" @default.
• W24816498 title "Integrated capillary electrophoresis amperometric detection microchip with replaceable microdisk working electrode" @default.
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• W24816498 doi "https://doi.org/10.1016/j.chroma.2005.05.032" @default.
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