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• W2481694313 endingPage "209" @default.
• W2481694313 startingPage "183" @default.
• W2481694313 abstract "The Mn2(CO)10 visible light photomediated polymerization of vinylidene fluoride (VDF) occurs readily in dimethyl carbonate from a variety of alkyl, semi- and perfluorinated halides at 40 °C, in low pressure glass tubes. Perfluoroalkyl iodide initiators also enable a controlled radical polymerization via iodine degenerative transfer (IDT) which proceeds with accumulation of the less reactive Pm-CF2-CH2-I vs. the Pn-CH2-CF2-I chain ends. Their subsequent quantitative activation by Mn2(CO)10 affords well-defined PVDF block copolymers." @default.
• W2481694313 created "2016-08-23" @default.
• W2481694313 creator A5009266365 @default.
• W2481694313 creator A5050532643 @default.
• W2481694313 creator A5051402281 @default.
• W2481694313 creator A5054657650 @default.
• W2481694313 creator A5068502039 @default.
• W2481694313 date "2015-01-01" @default.
• W2481694313 modified "2023-09-23" @default.
• W2481694313 title "Photochemically Enabled Iodine Degenerative Transfer Controlled Radical Homo- and Block Copolymerization of Vinylidene Fluoride at Ambient Temperatures with Mn₂(CO)₁₀ and Visible Light" @default.
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