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- W2482002180 abstract "The cation site population is used for monitoring the cation-framework interaction energy in hydrated K-Y-type zeolites with varying Si/Al ratio. The K-ion content of a series of Y-type zeolites was modified by (i) changing the framework Al content (by direct synthesis or by dealumination) and by (ii) exchange with NH4 cations, and their structures determined with X-ray powder methods. The population of site I with K ions depends primarily on the framework Al content, and is empty for Si:Al ratios over 2.7. The sites I' and II depopulate much more slowly. The cation distribution pattern seems to be determined by the short-range cation-framework interaction energy only, independent of the details of the population of the other sites (at high cation loading, the site I-site I' repulsion becomes important however). This is in agreement with recent statistical-thermodynamical developments." @default.
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- W2482002180 date "1988-05-27" @default.
- W2482002180 modified "2023-09-27" @default.
- W2482002180 title "Long-Range Versus Short-Range Effects in the Distribution of K Ions in Hydrated KY Zeolites" @default.
- W2482002180 doi "https://doi.org/10.1021/bk-1988-0368.ch012" @default.
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